Chemistry - A European Journal p. 6606 - 6609 (2011)
Update date:2022-08-05
Topics:
Specht, Zephen G.
Cortes-Llamas, Sara A.
Tran, Hai N.
Van Niekerk, Christoffel J.
Rancudo, Khing T.
Golen, James A.
Moore, Curtis E.
Rheingold, Arnold L.
Dwyer, Tammy J.
Grotjahn, Douglas B.
Functionalized carbene ligands: Increasing the steric bulk of R1 on 1 from H to tBu results in lengthening of the M-N bond (by up to 9 %), lowered activation energy for chelate opening (cf. 2) by 17 kcal mol -1, and improved binding
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