GEMINAL SYSTEMS. 50. SOLVOLYSIS OF 1-TOSYLOXY-Δ2-1,2,3-TRIAZOLINE-5,5-DICARBOXYLATE ESTERS AND THE STRUCTURE OF THE SOLVOLYSIS PRODUCT, O-TOSYL-N-α,α-BIS(ETHOXYCARBONYL)-β-METHOXYETHYLHYDROXYLAMINE

DOI: 10.1007/BF00961496

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1651 - 1657 (1990)

Update date:2022-07-30

Topics:

Authors:

Shustov, G. V.

Zolotoi, A. B.

Belov, P. N.

Konovalikhin, S. V.

Atovmyan, L. O.

et al. et al.

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Article abstract of DOI:10.1007/BF00961496

Solvolysis of 1-tosyloxy-Δ²-1,2,3-triazoline-5,5-dicarboxylic acid esters (1) occurs via elimination of N2 and leads predominantly to N-β-hydroxylethyl-O-tosylhydroxylamines (II), whose structure was determined unequivocally by x-ray structural

Full text of DOI:10.1007/BF00961496

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