Biomimetic oxidation of vitamin D by iron-sulfur model cluster and dioxygen system

DOI: 10.1016/S0040-4039(00)97764-5

Source and publish data:

Tetrahedron Letters p. 4903 - 4906 (1990)

Update date:2022-08-05

Topics:

Authors:

Yamamoto

Imae Imae

Yamada Yamada

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Article abstract of DOI:10.1016/S0040-4039(00)97764-5

Oxidation of vitamin D₃ with a combination of iron-sulfur protein model cluster, (n-Bu₄N)₂[Fe₄S₄(SPh)₄], and molecular oxygen produced (5E)-10-oxo-10-norvitamin D₃ and 8α-hydroxy-9,10-seco-4,6,10(19)-cholestatrien-3-one, a new type of vitamin D metabolites, mimicking biological oxidation.

Full text of DOI:10.1016/S0040-4039(00)97764-5

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