One-Pot Preparation of 1-Acyl-1-methoxycarbonyloxiranes and 1-Acyl-1-cyanooxiranes from Methyl 3-Hydroxy-2-methylenealkanoates or 3-Aryl-3-hydroxy-2-methylenepropanenitriles

DOI: 10.1055/s-1990-27016

Source and publish data:

Synthesis p. 787 - 789 (1990)

Update date:2022-08-03

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Authors:

Foucaud, Andre

Rouille, Eliane de

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Article abstract of DOI:10.1055/s-1990-27016

The reaction of sodium hypochlorite with methyl 3-hydroxy-2-methylenealkanoates or 3-aryl-3-hydroxy-2-methylenepropanenitriles, dispersed on silica gel, in acetonitrile leads to oxidation of the alcohol function and epoxidation of the methylene group to g

Full text of DOI:10.1055/s-1990-27016

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Product name:2-(α-Acetoxybenzyl)-2-methoxycarbonyloxirane

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