Chemistry of Heterocyclic Compounds p. 681 - 682 (1990)
Update date:2022-08-03
Topics:
Shachkus, A. A.
Degutis, Yu. A.
Myadyakshene, G. S.
Alkylation of 2,3,3-trimethyl- and 2,3,3,5-tetramethyl-3H-indoles with 2-bromomethylbenzonitrile gave 2-methylene-1-(2-cyanobenzyl)-2,3-dihydro-1H-indoles.When reacted with lithium aluminum hydride the latter are cyclized to 11,12,12a,13-tetrahydro-6H-indolo<1,2-b><2,4>benzodiazepines.
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