Novel Methodology for the Synthesis of trans-Alkene Dipeptide Isosteres

DOI: 10.1021/jo00006a027

Source and publish data:

Journal of Organic Chemistry p. 2107 - 2111 (1991)

Update date:2022-07-29

Topics:

Authors:

Shue, Youe-Kong

Carrera, George M.

Tufano, Michael D.

Nadzan, Alex M.

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Article abstract of DOI:10.1021/jo00006a027

Natural amino acids were converted to the corresponding allylic alcohols A, from which key precursors C were obtained via a three-step sequence <(a) Ac2O/Py or CbzOSu/Et3N/DMAP; (b) NMO/NaIO4/OsO4(cat.); (c) Ph3P=CR2CO2Bn>.The allylic alcohols D were furt

Full text of DOI:10.1021/jo00006a027

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