Synthesis and Reactivity of (1S,4S,5S)-5-Bromo-1,3,3-trimethyl-N-nitro-2-oxabicyclooctan-6-imine. X-Ray Molecular Structure and Absolute Configuration of E and Z Isomers of (1S,4S)-5,5-Dibromo-1,3,3-trimethyl-N-nitro-2-oxabicyclooctan-6-imin

DOI: 10.1039/P19900003053

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 3053 - 3059 (1990)

Update date:2022-08-04

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Authors:

Ranise, Angelo

Bondavalli, Francesco

Schenone, Pietro

Mugnoli, Angelo

Pani, Marcella

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Article abstract of DOI:10.1039/P19900003053

The potassium salt 2 of 1,3,3-trimethyl-N-nitro-2-oxabicyclo<2.2.2>octan-6-imine 1 reacted with bromine in acetic acid solution to give (1S,4S,5S)-5-bromo-1,3,3-trimethyl-N-nitro-2-oxabicyclo<2.2.2>octan-6-imine 3.Bromination of the salt 2 in methanolic p

Full text of DOI:10.1039/P19900003053

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