ANTHRACYCLINONES. PART VIII. SYNTHESIS OF A 9-METHYL ANTHRACYCLINONE FROM D-GLUCOSE

DOI: 10.1016/S0040-4020(01)81581-7

Source and publish data:

Tetrahedron p. 4885 - 4892 (1992)

Update date:2022-08-03

Topics:

Authors:

Deguin, Brigitte

Bertounesque, Emmanuel

Gaudel, Gilbert

Florent, Jean-Claude

Monneret, Claude

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Article abstract of DOI:10.1016/S0040-4020(01)81581-7

The chiral pool synthesis of enantiomerically pure anthracyclinone 6 from leucoquinizarin 10, and from 3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-α-D-ribo-pentodialdo-1,4-furanose (9) readily obtained from diacetone glucose, is reported.

Full text of DOI:10.1016/S0040-4020(01)81581-7

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Product name:3-O-benzyl-1,2-O-isopropylidene-3-C-methyl-5-(9',10'dihydro-1',4'-dihydroxy-9',10'-dioxo-2'-anthryl)-α-D-ribofuranose

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