Journal of the Chemical Society. Chemical communications p. 1490 - 1492 (1983)
Update date:2022-07-29
Topics:
Holmes, Andrew B.
Raithby, Paul R.
Thompson, John
Baxter, Andrew J. G.
Dixon, John
Treatment of the 2-azabicyclo<2.2.2>oct-5-ene imino Diels-Alder adduct (2) with N-bromosuccinimide in aqueous dimethoxyethane gives the rearranged bromohydrin (4a), whose structure is confirmed by X-ray crystallographic analysis, and which serves as a precursor to the 6-azabicyclo<3.2.1>octan-4-one (7).
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