Photoreduction of Aromatic Ketones in Hexamethylphosphoric Triamide (HMPA): Formation of Stable Coupling Products with HMPA

DOI: 10.1246/bcsj.63.3698

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3698 - 3700 (1990)

Update date:2022-08-05

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Authors:

Kohmoto, Shigeo

Kreher, Thomas

Yamamoto, Makoto

Yamada, Kazutoshi

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Article abstract of DOI:10.1246/bcsj.63.3698

Irradiation of aromatic carbonyl compounds in hexamethylphosphoric triamide (HMPA) resulted in the cross-coupling of ketyl radicals with the HMPA-derived radical generated via hydrogen abstraction from it.The results on acetolysis, methanolysis, and the r

Full text of DOI:10.1246/bcsj.63.3698

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