DIASTEREOSELECTIVE ALKYLATION OF CHIRAL TIN(II) ENOLATES ONTO CYCLIC ACYL IMINIUM IONS. ASYMMETRIC TOTAL SYNTHESIS OF (-)-SUPINIDINE

DOI: 10.1016/S0040-4020(01)96008-9

Source and publish data:

Tetrahedron p. 6361 - 6380 (1990)

Update date:2022-08-05

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Authors:

Nagao, Yoshimitsu

Dai, Wei-Min

Ochiai, Masahito

Shiro, Motoo

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Article abstract of DOI:10.1016/S0040-4020(01)96008-9

The scope and mechanism of the asymmetric alkylation of chiral tin(II) enolate 10 with cyclic acyl iminium ion 5 were investigated.An application of the reaction to the asymmetric synthesis of (-)-supinidine was also achieved.

Full text of DOI:10.1016/S0040-4020(01)96008-9

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