Diastereoselective Addition of a Silylketene Acetal to Chiral α-Thioaldehydes

DOI: 10.1016/S0040-4039(00)97160-0

Source and publish data:

Tetrahedron Letters p. 6733 - 6736 (1990)

Update date:2022-08-03

Topics:

Authors:

Annunziata, Rita

Cinquini, Mauro

Cozzi, Franco

Cozzi, Pier Giorgio

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)97160-0

Chiral α-thioaldehydes 2-6 undergo chelation or non-chelation controlled addition of silylketene acetal 1, depending on the nature of the Lewis acid catalyst and of the ligands at the stereocenter.

Full text of DOI:10.1016/S0040-4039(00)97160-0

Products guided by the article

Product name:2,2,5-Trimethyl-3-hydroxy-4-(phenylthio)hexanoic acid methyl ester

Cas No:132331-39-6

R&D Labs maybe for 132331-39-6

Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Wuxi Zuping Food Science And Technology Co.,LTD.

Contact:+86-510-87210822

Address:Guanlin town
Nanjing Duly Biotech Co., Ltd

website:http://www.dulynet.com/

Contact:025-84699383 -8003

Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China

Relevant to this article

Clefts in Simple Acyclic Organic Molecules. Correlated Stereodynamics of N-tert-Alkylbenzylamines Studied by Dynamic NMR Spectroscopy, X-ray Diffraction, and Molecular Mechanics Calculations

Doi:10.1021/jo00005a016
(1991)
Dynamic topochemical reaction control-A principle and its application in ansa-metallocene synthesis

Doi:10.1021/om100467y
(2010)
Synthesis and evaluation of oligodeoxynucleotides containing 3'-O-ethyl- 4'-C-(hydroxymethyl)thymidine: Introduction of a novel class of phosphodiester internucleoside linkages

Doi:10.1080/15257779408010674
(1994)
Oxovanadium(V)-Catalyzed Direct Amination of Allyl Alcohols

Doi:10.1002/cctc.201801841
(2019)
Stereocontrolled Synthesis of (+/-)-Acorenone B Based on New Ring Conversion

Doi:10.1039/c39900001778
(1990)
The Reaction of Ozonides from Mono-substituted Alkenes with Stabilized Phosphorus Ylides

Doi:10.1039/c39900001627
(1990)

Article Doi