NITROCYCLOPROPANES FROM NITRODIAZOMETHANES. PREPARATION AND REACTIVITY

DOI: 10.1016/S0040-4020(01)89052-9

Source and publish data:

Tetrahedron p. 7341 - 7358 (1990)

Update date:2022-08-06

Topics:

Authors:

O'Bannon, P. E.

Dailey, William P.

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Article abstract of DOI:10.1016/S0040-4020(01)89052-9

Nitrodiazo compounds cyclopropanate electron rich alkenes in the presence of rhodium(II) acetate.The yields and diastereoselectivities are dependent on both the alkene and the nitrodiazo precursor.Nitrocyclopropanecarboxylates undergo ring opening, reduct

Full text of DOI:10.1016/S0040-4020(01)89052-9

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