Differential Use of the Pyranoside Ring for Stereocontrolled Routes to Triquinanes: Silphinene and Silphiperfolene Skeleta

DOI: 10.1039/c39900001440

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1440 - 1443 (1990)

Update date:2022-08-05

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Authors:

Dickson, John K.

Fraser-Reid, Bert

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Article abstract of DOI:10.1039/c39900001440

The use of the pyranosidodiquinane 7 as a key intermediate for constructing the skeleta of 1 and 2 involving a procedure in which all of the stereochemistry is established at the level of 7 before the sugar residue is utilized to obtain this ring.

Full text of DOI:10.1039/c39900001440

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