Journal of the Chemical Society. Perkin transactions I p. 3215 - 3217 (1990)
Update date:2022-09-26
Topics:
Naemura, Koichiro
Furutani, Atsushi
2,6-Bis(acetoxymethyl)-2,6-bis(hydroxymethyl)spiro<3.3>heptane with axial chirality and moderate optical purity has been prepared in high chemical yield by pig liver esterase-catalysed asymmetric hydrolyses of 2,2,6,,6-tetrakis(acetoxymethyl)spiro<3.3>heptane.Similarly, racemic 2,6-disubstituted spiro<3.3>heptane derivatives with axial chirality were resolved by enantioselective enzime-catalysed hydrolyses.
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