Asymmetric Reduction of Prochiral Aromatic Ketones by Borane-Amine Complexes in the Presence of a Chiral Amine-BF3 Catalyst

DOI: 10.1039/c39900001145

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1145 - 1147 (1990)

Update date:2022-08-03

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Authors:

Kanth, J. V. Bhaskar

Periasamy, Mariappan

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Article abstract of DOI:10.1039/c39900001145

The (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BH3 complex reduces aromatic ketones to alcohols with 11-57 percent enantiomeric excess (e.e.) in the presence of BF3*OEt2; the (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BF3 complex catalyses asymm

Full text of DOI:10.1039/c39900001145

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