Asymmetric Reduction of Prochiral Aromatic Ketones by Borane-Amine Complexes in the Presence of a Chiral Amine-BF3 Catalyst

DOI: 10.1039/c39900001145

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1145 - 1147 (1990)

Update date:2022-08-03

Topics:

Authors:

Kanth, J. V. Bhaskar

Periasamy, Mariappan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001145

The (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BH3 complex reduces aromatic ketones to alcohols with 11-57 percent enantiomeric excess (e.e.) in the presence of BF3*OEt2; the (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BF3 complex catalyses asymm

Full text of DOI:10.1039/c39900001145

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-(1-Phenyl-ethyl)-4,5-dihydro-3H-4-aza-cyclohepta[2,1-a;3,4-a']dinaphthalene

Cas No:132666-12-7

R&D Labs maybe for 132666-12-7

Hefei Highzone Fine Chemical S&T CO.,LTD

Contact:86-0551-63663560

Address:room 1801 NO. 24 Shuguang RD.
Shanghai Bocimed Pharmaceutical Co., Ltd.

website:http://www.bocimed.com

Contact:+86-21-68861632

Address:Building 1, Lane 647, Songtao Road, Zhangjiang High-Tech Park, Shanghai
Zhejiang Haizhou Pharmaceutical Co., Ltd.

website:https://www.haizhoupharma.com/

Contact:+86-576-88221016

Address:No. 19, Donghai 5th Avenue, Yanhai Industrial Zone, Linhai, Zhejiang, China
SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
Hangzhou TJM Chemical Trade Co., Ltd

Contact:86-571-88223276 86-13388481653

Address:2221#,Boyuexuan,1860# Binsheng Road,Binjiang District, Hangzhou CityZhejiang Province, 310051, P. R. China

Relevant to this article

Copper-Catalyzed Selective ortho-C-H/N-H Annulation of Benzamides with Arynes: Synthesis of Phenanthridinone Alkaloids

Doi:10.1021/acs.orglett.7b00442
(2017)
Electrophilic aromatic substitutions of aryltrifluoroborates with retention of the BF₃^- group: Quantification of the activating and directing effects of the trifluoroborate group

Doi:10.1021/ja4017655
(2013)
Discovery of novel S1P₂ antagonists, part 3: Improving the oral bioavailability of a series of 1,3-bis(aryloxy)benzene derivatives

Doi:10.1016/j.bmcl.2016.01.031
(2016)
Synthesis and degradation of backbone photodegradable polyester dendrimers

Doi:10.1021/ol4004367
(2013)
Two different dimensional bbbm-based cobalt(II) coordination polymers tuned by benzenedicarboxylates: Assembly, structures and properties

Doi:10.1016/j.ica.2012.11.024
(2013)
Asymmetric Aldol Reactions Employing a Camphor-Derived Chiral Oxazinone Auxiliary

Doi:10.1021/jo00045a010
(1992)

Article Doi