Asymmetric Reduction of Prochiral Aromatic Ketones by Borane-Amine Complexes in the Presence of a Chiral Amine-BF3 Catalyst

DOI: 10.1039/c39900001145

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1145 - 1147 (1990)

Update date:2022-08-03

Topics:

Authors:

Kanth, J. V. Bhaskar

Periasamy, Mariappan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39900001145

The (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BH3 complex reduces aromatic ketones to alcohols with 11-57 percent enantiomeric excess (e.e.) in the presence of BF3*OEt2; the (-)-N-α-methylbenzyl-3,5-dihydrodinaphthazepine-BF3 complex catalyses asymm

Full text of DOI:10.1039/c39900001145

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:4-(1-Phenyl-ethyl)-4,5-dihydro-3H-4-aza-cyclohepta[2,1-a;3,4-a']dinaphthalene

Cas No:132666-12-7

R&D Labs maybe for 132666-12-7

uni source industries limited

Contact:86 21 3772 9386

Address:Rm.1803,Starry Bldg.1,1505 Meijiabang Road,Shanghai 201620 China
Sino Rarechem Labs Co.Ltd

Contact:+86-0512-62857507

Address:Boji Science Park, No1688C,Taishan road, Suzhou ,China
Jiangyin Tenghua Import&Export Co.,Ltd.

Contact:+86-510-86263875

Address:Room 402-B,9 Yanling Road, Jiangyin,Jiangsu, China
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Shandong Topscience Biotech Co., Ltd.

Contact:0633-2619278

Address:No. 98 Lanshan West Road, Lanshan District, Rizhao, Shandong Province, P.R. of China

Relevant to this article

Copper-Catalyzed Selective ortho-C-H/N-H Annulation of Benzamides with Arynes: Synthesis of Phenanthridinone Alkaloids

Doi:10.1021/acs.orglett.7b00442
(2017)
Electrophilic aromatic substitutions of aryltrifluoroborates with retention of the BF₃^- group: Quantification of the activating and directing effects of the trifluoroborate group

Doi:10.1021/ja4017655
(2013)
Discovery of novel S1P₂ antagonists, part 3: Improving the oral bioavailability of a series of 1,3-bis(aryloxy)benzene derivatives

Doi:10.1016/j.bmcl.2016.01.031
(2016)
Synthesis and degradation of backbone photodegradable polyester dendrimers

Doi:10.1021/ol4004367
(2013)
Two different dimensional bbbm-based cobalt(II) coordination polymers tuned by benzenedicarboxylates: Assembly, structures and properties

Doi:10.1016/j.ica.2012.11.024
(2013)
Asymmetric Aldol Reactions Employing a Camphor-Derived Chiral Oxazinone Auxiliary

Doi:10.1021/jo00045a010
(1992)

Article Doi