REGIO- AND STEREOSELECTIVE CONTROL IN THE ALKYLATION OF 1-ALKOXY-1,4-CYCLOHEXADIENES BY THE CHIRAL AUXILIARY APPROACH. ENANTIOSELECTIVE SYNTHESIS OF PRECURSORS FOR CIS-HYDRINDANES.

DOI: 10.1016/S0957-4166(00)80546-7

Source and publish data:

Tetrahedron Asymmetry p. 547 - 560 (1990)

Update date:2022-08-04

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Authors:

Stanssens, Dirk

Keukeleire, Denis De

Vandewalle, Maurits

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Article abstract of DOI:10.1016/S0957-4166(00)80546-7

A method is described for the regio- and diastereoselective alkylation of optically active 1-alkoxy-1,4-cyclohexadienes.Reaction conditions were optimised for substrates 4a with the per-O-methyl-β-D-glucopyranosyl group as chiral auxiliary.In the methylat

Full text of DOI:10.1016/S0957-4166(00)80546-7

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