TRIFLUOROPROPENE OXIDE AS A TRIFLUOROMETHYL SOURCE. PREPARATION OF OPTICALLY ACTIVE ALCOHOLS

DOI: 10.1016/S0040-4039(00)97235-6

Source and publish data:

Tetrahedron Letters p. 7031 - 7034 (1990)

Update date:2022-07-29

Topics:

Authors:

Takahashi, Osamu

Furuhashi, Keizo

Fukumasa, Mitsuo

Hirai, Toshihiro

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Article abstract of DOI:10.1016/S0040-4039(00)97235-6

Optically active 3,3,3-trifluoropropene oxide (TFPO) was converted to 1,1,1-trifluoro-2-ols via Grignard type or Friedel-Crafts type reaction.The regio-selectivity of the latter reaction was discussed through an MO calculation.

Full text of DOI:10.1016/S0040-4039(00)97235-6

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