STUDIES ON N-METALLO IMINES: SYNTHESIS OF N-UNSUBSTITUTED AZIRIDINES FROM N-TRIMETHYLSILYL IMINES AND LITHIUM ENOLATES OF α-HALO ESTERS.

DOI: 10.1016/S0040-4039(00)71234-2

Source and publish data:

Tetrahedron Letters p. 121 - 124 (1991)

Update date:2022-07-29

Topics:

Authors:

Cainelli, Gianfranco

Panunzio, Mauro

Giacomini, Daria

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Article abstract of DOI:10.1016/S0040-4039(00)71234-2

Addition of lithium enolates of 2-halo carboxylic esters to N-trimethylsilyl imines results in the formation of 1H-aziridine derivatives, in the Darzens fashion, with high cis-selectivity.

Full text of DOI:10.1016/S0040-4039(00)71234-2

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