Tetrahedron Letters p. 5293 - 5296 (1990)
Update date:2022-08-04
Topics:
Lewis, Frederick D.
Reddy, G. Dasharatha
Irradiation of N-alkyl-5-phenyl-4-penten-1-amines results in the formation of intramolecular styrene-amine adducts and disproportionation products.Increasing the bulk of the N-alkyl group increases the regioselectivity of N-H transfer favoring the formation of piperidine vs. pyrrolidine products and favors disproportionation vs. cyclization.
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