Tetrahedron Letters p. 335 - 338 (1991)
Update date:2022-08-04
Topics:
Tahir, S. Hasan
Olmstead, Marilyn M.
Kurth, Mark J.
Diastereoselective S-allylation of thioxanone 6 and subsequent ylid formation/<2,3>-sigmatropic rearrangement delivers excellent Cα-induction.Non-stereospecific Cβ-induction results from scrambling of olefin geometry in the S-allylation step.
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