Synthetic Studies of Diels-Alder Adduct of Furan. Formal Total Synthesis of (+/-)-Avenaciolide

DOI: 10.1246/bcsj.59.3881

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3881 - 3884 (1986)

Update date:2022-09-26

Topics:

Authors:

Kotsuki, Hiyoshizo

Ohnishi, Hiroyuki

Akitomo, Yasuhiro

Ochi, Masamitsu

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Article abstract of DOI:10.1246/bcsj.59.3881

The endo-Diels-Alder adduct of furan with methyl acrylate was transformed into a bis-γ-lactone derivative which is a well-known precursor for the synthesis of (+/-)-avenaciolide.The route involves 13 steps and the overall yield was 17.9percent.

Full text of DOI:10.1246/bcsj.59.3881

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