Enantioselective Chiral Borane-Mediated Aldol Reactions of Silyl Ketene Acetals with Aldehydes. Novel Effect of the Trialkylsilyl Group of the Silyl Ketene Acetal on the Reaction Course

DOI: 10.1021/jo00007a003

Source and publish data:

Journal of Organic Chemistry p. 2276 - 2278 (1991)

Update date:2022-09-26

Topics:

Authors:

Kiyooka, Syun-ichi

Kaneko, Yuichi

Komura, Misako

Matsuo, Hidehito

Nakano, Masahito

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00007a003

Highly enantioselective aldol reactions of silyl ketene acetals with a variety of aldehydes were achieved by using chiral boranes prepared from the sulfonamides of α-amino acids.

Full text of DOI:10.1021/jo00007a003

Products guided by the article

Product name:3-(tert-Butyl-dimethyl-silanyloxy)-3-ethoxy-1-phenyl-propan-1-ol

Cas No:133270-78-7

R&D Labs maybe for 133270-78-7

Zhejiang Quzhou Zhengbang Organosilicon Co.,ltd.

Contact:86-570-3375195

Address:No.17 Lingqing Road technology industry,Quzhou City,Zhejiang Province,China
Angel Yeast Co., Ltd.

Contact:+86-717-6370352

Address:168 Chengdong Avenue, Yichang, Hubei 443003, P. R.China
Meryer (Shanghai) Chemical Technology Co., Ltd.

website:http://www.meryer.com/cn/index/

Contact:+86-755-86170518

Address:Minhang,Shanghai, China
Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Luojiang Chenming Biological Products Co

Contact:+86 15000297032

Address:GROUP NO.4, HE SHENG VILLAGE, PANLONG TOWN,

Relevant to this article

Asymmetric formal synthesis of (+)-pyrenolide D

Doi:10.1055/s-0033-1338584
(2014)
Design and synthesis of novel amide AKT1 inhibitors with selectivity over CDK2

Doi:10.1016/j.bmcl.2011.07.056
(2011)
Interception of a rautenstrauch intermediate by alkynes for [5+2] cycloaddition: Rhodium-catalyzed cycloisomerization of 3-acyloxy-4-ene-1,9- diynes to bicyclo[5.3.0]decatrienes

Doi:10.1002/anie.201103136
(2011)
Silver-catalyzed intramolecular aminofluorination of activated allenes

Doi:10.1002/anie.201103225
(2011)
Phosphane-free copper-catalyzed decarboxylative coupling of alkynyl carboxylic acids with aryl halides under aerobic conditions

Doi:10.1002/ejoc.201100659
(2011)
Diastereoselective cascade reactions toward substituted diazaindeno[2,1-α]phenanthrenes

Doi:10.1016/j.tet.2011.07.050
(2011)

Article Doi