Enantioselective Chiral Borane-Mediated Aldol Reactions of Silyl Ketene Acetals with Aldehydes. Novel Effect of the Trialkylsilyl Group of the Silyl Ketene Acetal on the Reaction Course

DOI: 10.1021/jo00007a003

Source and publish data:

Journal of Organic Chemistry p. 2276 - 2278 (1991)

Update date:2022-09-26

Topics:

Authors:

Kiyooka, Syun-ichi

Kaneko, Yuichi

Komura, Misako

Matsuo, Hidehito

Nakano, Masahito

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Article abstract of DOI:10.1021/jo00007a003

Highly enantioselective aldol reactions of silyl ketene acetals with a variety of aldehydes were achieved by using chiral boranes prepared from the sulfonamides of α-amino acids.

Full text of DOI:10.1021/jo00007a003

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