
Tetrahedron Letters p. 6167 - 6170 (1990)
Update date:2022-08-03
Topics:
Ernst, Beat
Mesmaeker, Alain De
Wagner, Beatrice
Winkler, Tammo
Carbohydrate exo 1,2-orthoesters are obtained in good to excellent yields by treating furanose and pyranose hemiacetals first with 1.1 eq. 1-chloro-2,N,N-trimethyl-propenylamine and then with the appropriate alcohols in the presence of NEt3.
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