Manganese Carbonyl and Phase Transfer catalysed, Stereospecific Hydroacylation of Allenes to α,β-Unsaturated Ketones

DOI: 10.1039/c39910000008

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 8 - 9 (1991)

Update date:2022-08-05

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Authors:

Satyanarayana, Nistala

Alper, Howard

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Article abstract of DOI:10.1039/c39910000008

Phase transfer (5 mmol dm^-3 NaOH, CH2Cl2, cetyltrimethylammonium bromide) catalysed reaction of allenes with carbon monoxide, decacarbonyldimanganese and methyl iodide affords α,β-unsaturated ketones in a stereospecific process.

Full text of DOI:10.1039/c39910000008

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