Asymmetric Diels-Alder Cycloadditions with C2-Symmetrical Chiral Carbamoylnitroso Dienophiles

DOI: 10.1002/hlca.19910740112

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Helvetica Chimica Acta p. 103 - 109 (1991)

Update date:2022-07-29

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Authors:

Defoin, Albert

Brouillard-Piochet, Agnes

Streith, Jacques

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Article abstract of DOI:10.1002/hlca.19910740112

The C₂-symmetrical chiral pyrrolidines 2 and 3 are of opposite helicity.The corresponding N-acylnitroso dienophiles 6 and 7 react in good yield with cyclohexadiene, leading thereby with excellent diastereoisomeric excess to the expected Diels-A

Full text of DOI:10.1002/hlca.19910740112

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