Tetrahedron p. 457 - 480 (1991)
Update date:2022-08-02
Topics:
Baldwin, J. E.
Bradley, M.
Adlington, R. M.
Norris, W. J.
Turner, N. J.
Incubation of δ-L-α-aminoadipoyl-L-<3-13C>cysteinyl-D-<3-2H>valine with Isopenicillin N Synthase (IPNS) resulted of a 'shunt metabolite', which we believe is formed from the collapse of an enzyme bound monocyclic β-lactam intermediate.Chemical studies int
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