Synthesis of 2-spirocyclopropylglucose via condensation of erythrose with the lithium enolate of 2,6-di-tert=butyl-4-methylphenyl cyclopropanecarboxylate

DOI: 10.1016/S0040-4039(00)79465-2

Source and publish data:

Tetrahedron Letters p. 449 - 452 (1991)

Update date:2022-09-26

Topics:

Authors:

Petter, Russell C.

Kumaravel

Powers, David G.

Chang, Chi-Tai

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)79465-2

Glyceraldehyde, erythrose, and threose are condensed with the enolate derived from cyclopropanecarboxylic acid BHT ester. The conversion of two diastereomeric products of this condensation into new 2-spirocyclopropyl-substituted aldopyranoses is described.

Full text of DOI:10.1016/S0040-4039(00)79465-2

Products guided by the article

Product name:1-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-cyclopropanecarboxylic acid 2,6-di-tert-butyl-4-methyl-phenyl ester

Cas No:133463-08-8

R&D Labs maybe for 133463-08-8

ZUNYI CITY BEI YUAN CHEMICAL CO., LTD

website:http://www.china-beiyuan.com

Contact:+86-851-27751258

Address:Shawan Town, Huichuan District, Zunyi City, Guizhou Province, China
xujianqiang

Contact:86-21-57725962

Address:shanghai
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
Shanghai Yudiao Chemistry Technology Co.,Ltd

Contact:0086-18964703211

Address:Building NO.5, NO.218,Rongtian Road,ganxiang town,Jinshan District,shanghai,201518,china

Relevant to this article

A fluorescent turn-on probe for the detection of alkaline phosphatase activity in living cells

Doi:10.1039/c1cc13819g
(2011)
Aryl aldehydes as traceless dielectrophiles in bifunctional titanocene-catalyzed propargylic C-X activations

Doi:10.1021/ol202401n
(2011)
Synthesis and bioevaluation of new 5-benzylidenethiazolidine-2,4-diones bearing benzenesulfonamide moiety

Doi:10.1007/s00044-015-1422-9
(2015)
Imidazo[2,1-b]thiazole guanylhydrazones as RSK2 inhibitors

Doi:10.1016/j.ejmech.2011.07.001
(2011)
The effect of central bond torsional mobility on the Rydberg state ring opening of alkylcyclobutenes

Doi:10.1139/v03-058
(2003)
Chiral pyridin-3-ones and pyridines: Syntheses of enantiopure 2,4-disubstituted 6-hydroxy-1,6-dihydro-2h-pyridin-3-ones, 2,3-disubstituted 4-iodopyridines, and enantiopure 2,3-disubstituted 4-pyridinemethanols

Doi:10.1021/jo201662n
(2011)

Article Doi