Synthesis of 2-spirocyclopropylglucose via condensation of erythrose with the lithium enolate of 2,6-di-tert=butyl-4-methylphenyl cyclopropanecarboxylate

DOI: 10.1016/S0040-4039(00)79465-2

Source and publish data:

Tetrahedron Letters p. 449 - 452 (1991)

Update date:2022-09-26

Topics:

Authors:

Petter, Russell C.

Kumaravel

Powers, David G.

Chang, Chi-Tai

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Article abstract of DOI:10.1016/S0040-4039(00)79465-2

Glyceraldehyde, erythrose, and threose are condensed with the enolate derived from cyclopropanecarboxylic acid BHT ester. The conversion of two diastereomeric products of this condensation into new 2-spirocyclopropyl-substituted aldopyranoses is described.

Full text of DOI:10.1016/S0040-4039(00)79465-2

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Product name:1-[((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-hydroxy-methyl]-cyclopropanecarboxylic acid 2,6-di-tert-butyl-4-methyl-phenyl ester

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