Cycloaddition-Elimination Reactions of Freund's "Methyl Isothiocyanate Sulfide" with Electrophilic Nitriles

DOI: 10.1021/jo00010a018

Source and publish data:

Journal of Organic Chemistry p. 3268 - 3270 (1991)

Update date:2022-08-04

Topics:

Authors:

L'abbe, Gerrit

Vandendriessche, Anna

Sannen, Ingrid

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00010a018

The 1,2,4-dithiazolidine 1 and the 1,2,4-thiadiazolidine 2 are interconvertible in the presence of electrophilic nitriles and furnish 1,2,4-thiadiazoline-5-thiones 7 as final products.A mechanistic rationalization involving consecutive cycloaddition-elimi

Full text of DOI:10.1021/jo00010a018

Products guided by the article

Product name:4-methyl-3-(p-toluenesulfonyl)-1,2,4-thiadiazoline-5-thione

Cas No:133523-50-9

R&D Labs maybe for 133523-50-9

Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
LinHai Cina Chemical Co., LTD.

Contact:0576-85580989

Address:Pharma-chem zone,Duqiao,Linhai,Zhejiang,China
Watson International Ltd

Contact:+44 (0)2036089360-31

Address:Chanceryhouse,Chancery Lan
Shandong Dayi Chemical Co., Ltd.

website:http://www.dayi.com.cn

Contact:+86- 535-7388728. 15306386031

Address:No 1 Danya west road, Laiyang City, Shandong province
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China

Relevant to this article

Functionalized ionic liquids with highly polar polyhydroxylated appendages and their rapid synthesis via thiol-ene click chemistry

Doi:10.1016/j.tetlet.2011.07.126
(2011)
Efficient entry to the hasubanan alkaloids: First enantioselective total syntheses of (-)-hasubanonine, (-)-runanine, (-)-delavayine, and (+)-periglaucine B

Doi:10.1002/anie.201102226
(2011)
Asymmetric chroman synthesis via an intramolecular oxy-Michael addition by bifunctional organocatalysts

Doi:10.1039/c3ob41938j
(2014)
New 2,3-disubstituted-5-hydroxyquinoxaline ligands and their coordination chemistry with cyclometallated iridium(iii): Syntheses, structures and tunable electronic properties

Doi:10.1039/c1dt10707k
(2011)
Asymmeric formal [3 + 3]-cycloaddition reactions of nitrones with electrophilic vinylcarbene intermediates

Doi:10.1021/ja207664r
(2011)
Characterization of Amphipathic Fluorinated Porphyrin Derivatives

Doi:10.1039/c39920000545
(1992)

Article Doi