Cycloaddition-Elimination Reactions of Freund's "Methyl Isothiocyanate Sulfide" with Electrophilic Nitriles

DOI: 10.1021/jo00010a018

Source and publish data:

Journal of Organic Chemistry p. 3268 - 3270 (1991)

Update date:2022-08-04

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Authors:

L'abbe, Gerrit

Vandendriessche, Anna

Sannen, Ingrid

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Article abstract of DOI:10.1021/jo00010a018

The 1,2,4-dithiazolidine 1 and the 1,2,4-thiadiazolidine 2 are interconvertible in the presence of electrophilic nitriles and furnish 1,2,4-thiadiazoline-5-thiones 7 as final products.A mechanistic rationalization involving consecutive cycloaddition-elimi

Full text of DOI:10.1021/jo00010a018

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