
Journal of the American Chemical Society p. 4218 - 4229 (1991)
Update date:2022-08-03
Topics:
Mulzer, Johann
Kattner, Lars
Strecker, Achim R.
Schr?der, Christian
Buschmann, Jürgen
Lehmann, Christian
Luger, Peter
The chromium(II)-mediated addition ("Hiyama reaction") of the chiral allylic bromides 13, 15, 19, 22, 24, and 27 to achiral and chiral aldehydes proceeds with high Felkin-Anh selectivity with respect to the stereocenter at Cγ in the bromide (Table II). By
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