Tetrahedron p. 431 - 442 (1992)
Update date:2022-08-04
Topics: Asymmetric synthesis Enantiomer Chiral Catalyst Derivatives Stereoselective synthesis Asymmetric Induction Heterocyclic compound
Agami, Claude
Couty, Francois
Poursoulis, Michel
Vaissermann, Jacqueline
Condensation of chiral N-homoallyl β-amino alcohols with glyoxal produces iminium ions which are cyclized with complete stereoselectivity.These substrates, whose reactivity is closely dependent on the substitution pattern of the ethylenic moiety, undergo
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