Journal of the American Chemical Society p. 3925 - 3934 (1991)
Update date:2022-08-04
Topics:
Kirmse, Wolfgang
H?mberger, Günter
Arylcarbenes with unsaturated ortho substituents (vinyloxy, 1-propenyloxy, allyl, 2-butenyl, 2,4-pentadienyl) were generated in methanol by photolysis of diazo precursors. Intermolecular OH insertion was found to compete with intramolecular addition to th
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