Tetrahedron Asymmetry p. 27 - 30 (1991)
Update date:2022-08-04
Topics:
Kim
Lee
Kim
Whang
Silyl nitronate cycloadditions to Oppolzer's chiral sultam derivatives, followed by the elimination of the silyl alcohols from the resulting N-silyloxyisoxazolidines, provide Δ2-isoxazolines in good stereoselectivity (ca. 89/11). The favored transition state is suggested in the light of the X-ray crystal structure of a major cycloadduct.
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