ON THE COHERENCE OF INCORPORATION OF THE FLUOROVINYL MOIETY INTO BIOACTIVE ORGANIC COMPOUNDS. SYNTHESIS OF AN INSECT JUVENILE HORMONE III FLUORINATED ANALOG.

DOI: 10.1016/S0040-4020(01)86022-1

Source and publish data:

Tetrahedron p. 5161 - 5168 (1988)

Update date:2022-08-03

Topics:

Authors:

Camps, F.

Messeguer, A.

Sanchez, Francisco-Jose

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86022-1

An insect juvenile hormone fluoroanalog, methyl 10-fluoro-10,11-epoxyfarnesoate (9), has been prepared, using tandem Claisen-Cope rearrangements on fluorovinyl intermediate 1 as a crucial step.Along this synthesis chemical and spectral data have been obtained that might question some applications of fluorovinyl derivatives in the design of bioactive organic compounds.

Full text of DOI:10.1016/S0040-4020(01)86022-1

Products guided by the article

Product name:methyl (2E)-6,7-epoxyfarnesoate

Cas No:133707-14-9

R&D Labs maybe for 133707-14-9

Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Anhui Charm Imp.&Exp.Co., Ltd

website:http://www.chinacharm.cn/

Contact:86 551 5316260

Address:No. 211,XiangZhang Road,Hefei City,Anhui Province,China
Shandong Xiangde Biotechnology Co., Ltd

Contact:+86 -15066639877

Address:Sanba street
Shandong Bolode Bio-Technology Co., LTD

Contact:+86-0531-58966870

Address:136 Jingyi Road,Huaiyin District,Jinan,Shandong,China
Shao Xing Empire Import&Export CO.,ltd

Contact:86-575-82127757

Address:11#, Weiwu Road, Shangyu Industrial Park, Hangzhou Bay, Hangzhou, Zhejiang Province, China

Relevant to this article

Micro-Cu₄I₄-MOF: Reversible iodine adsorption and catalytic properties for tandem reaction of Friedel-Crafts alkylation of indoles with acetals

Doi:10.1039/c6cc07027b
(2016)
Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in Situ IR spectroscopy

Doi:10.1021/jacs.8b06871
(2018)
Stereospecific Electrophilic Fluorination of Alkylcarbastannatrane Reagents

Doi:10.1002/anie.201704672
(2017)
Divergent synthetic routes for ring expansion or cyclization from 1,4-allylic diol derivatives via gold(I) catalysis or zinc(II) mediation

Doi:10.1021/jo2015517
(2011)
Ratiometric and simultaneous estimation of Fe³⁺ and Cu ²⁺ ions: 1,3,5-substituted triethylbenzene derivatives coupled with benzimidazole

Doi:10.1016/j.tetlet.2011.05.078
(2011)
Cyclization of 4,5-diamino pyrazole derivatives and their antibacterial activities

Doi:10.1002/cjoc.201180265
(2011)

Article Doi