ON THE COHERENCE OF INCORPORATION OF THE FLUOROVINYL MOIETY INTO BIOACTIVE ORGANIC COMPOUNDS. SYNTHESIS OF AN INSECT JUVENILE HORMONE III FLUORINATED ANALOG.

DOI: 10.1016/S0040-4020(01)86022-1

Source and publish data:

Tetrahedron p. 5161 - 5168 (1988)

Update date:2022-08-03

Topics:

Authors:

Camps, F.

Messeguer, A.

Sanchez, Francisco-Jose

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)86022-1

An insect juvenile hormone fluoroanalog, methyl 10-fluoro-10,11-epoxyfarnesoate (9), has been prepared, using tandem Claisen-Cope rearrangements on fluorovinyl intermediate 1 as a crucial step.Along this synthesis chemical and spectral data have been obtained that might question some applications of fluorovinyl derivatives in the design of bioactive organic compounds.

Full text of DOI:10.1016/S0040-4020(01)86022-1

Products guided by the article

Product name:methyl (2E)-6,7-epoxyfarnesoate

Cas No:133707-14-9

R&D Labs maybe for 133707-14-9

QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
BIOS CHEMICALS

Contact:+33-5-34012600

Address:28 ZA des Pignès
Shijiazhuang Yunxuan Im&Export Co.,Ltd.

Contact:+86-311-83037514

Address:No.6 Hongbin Road
Yangzhou Siyu Chemical Co.,Ltd.

Contact:+86-514-87325867 13358126196

Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Suzhou Sibian Chemical Technology Co., Ltd

website:http://www.sibianpharm.com

Contact:+8618169181984,+8618013186906

Address:Room1404,BuildingA,Jiabao Square No.323 Baodai East Road,Wuzhong District,Suzhou Jiangsu China (215128)

Relevant to this article

Micro-Cu₄I₄-MOF: Reversible iodine adsorption and catalytic properties for tandem reaction of Friedel-Crafts alkylation of indoles with acetals

Doi:10.1039/c6cc07027b
(2016)
Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in Situ IR spectroscopy

Doi:10.1021/jacs.8b06871
(2018)
Stereospecific Electrophilic Fluorination of Alkylcarbastannatrane Reagents

Doi:10.1002/anie.201704672
(2017)
Divergent synthetic routes for ring expansion or cyclization from 1,4-allylic diol derivatives via gold(I) catalysis or zinc(II) mediation

Doi:10.1021/jo2015517
(2011)
Ratiometric and simultaneous estimation of Fe³⁺ and Cu ²⁺ ions: 1,3,5-substituted triethylbenzene derivatives coupled with benzimidazole

Doi:10.1016/j.tetlet.2011.05.078
(2011)
Cyclization of 4,5-diamino pyrazole derivatives and their antibacterial activities

Doi:10.1002/cjoc.201180265
(2011)

Article Doi