ON THE COHERENCE OF INCORPORATION OF THE FLUOROVINYL MOIETY INTO BIOACTIVE ORGANIC COMPOUNDS. SYNTHESIS OF AN INSECT JUVENILE HORMONE III FLUORINATED ANALOG.

DOI: 10.1016/S0040-4020(01)86022-1

Source and publish data:

Tetrahedron p. 5161 - 5168 (1988)

Update date:2022-08-03

Topics:

Authors:

Camps, F.

Messeguer, A.

Sanchez, Francisco-Jose

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Article abstract of DOI:10.1016/S0040-4020(01)86022-1

An insect juvenile hormone fluoroanalog, methyl 10-fluoro-10,11-epoxyfarnesoate (9), has been prepared, using tandem Claisen-Cope rearrangements on fluorovinyl intermediate 1 as a crucial step.Along this synthesis chemical and spectral data have been obtained that might question some applications of fluorovinyl derivatives in the design of bioactive organic compounds.

Full text of DOI:10.1016/S0040-4020(01)86022-1

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Product name:methyl (2E)-6,7-epoxyfarnesoate

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