Tetrahedron p. 1231 - 1238 (1991)
Update date:2022-09-26
Topics:
Bessard, Ives
Schlosser, Manfred
Hydrogenolytic ring cleavage of gem-difluorocyclopropanes occurs exclusively at the carbon-carbon bond opposite to the halogen-bearing center and affords mainly gem-difluoroalkanes.The intermediacy of catalyst/cyclopropane derived adducts (e.g., palladocyclobutanes or 1,3-dipalladiopropanes) is postulated in order to rationalize the formation of monofluorinated and halogen-free by-products and, in addition, to explain specific substituent effects on the reaction rates.
View MoreKangZhiYuan Pharmaceutical Company Limited
Contact:(Sabrina)86-20-85273232
Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Contact:886 2 2541 0022
Address:8 Fl., No. 11, Sec. 1, Chung Shan North Rd., Taipei, Taiwan R.O.C.
Reliable Pharma Technology (Shanghai) Co., Ltd.
Contact:0086-21-67676847-8008
Address:Lane 1500, No.68, Xinfei Road, Songjiang District, Shanghai, 201611, P.R.China.
Jinan Aery Pharmaceutical Co,.Ltd
Contact:+8653181263406
Address:1-1916,Building1 Fenghuang SOHO,Fenghuang Road,High-tech Zone,Jinan,Shandong
Shanghai Sunway Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-5161 3915
Address:Shanghai YangPu
Doi:10.1016/j.bmcl.2011.08.059
(2011)Doi:10.1246/cl.2011.506
(2011)Doi:10.1021/ja208156z
(2011)Doi:10.1016/j.jcat.2011.07.011
(2011)Doi:10.1016/j.tetlet.2011.08.070
(2011)Doi:10.1134/S1070428011090235
(2011)
