Tetrahedron Letters p. 781 - 784 (1991)
Update date:2022-08-03
Topics:
Miyashita
Kawashima
Kaji
Nomura
Nohira
Co2(CO)8 catalyzed aminocarbonylation of geminal dihaloalkanes R2CX2 (R = H, CH3; X = Br, Cl) with NHEt2 affording R2C(NEt2)CONEt2 selectively in n-C6H14 using NEt3, while the yield of R2C(CONEt2)2 fairly increased in THF or benzene in aid of K2CO3.
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(1991)
