Acylation and Esterification of the Aryloxide Ligand in . Crystal Structures of , Hbhmap and O=C(dbmp)But (Hdbmp = 2,6-di-tert-butyl-4-methylphenol, Hbhmap = 3-tert-butyl-2-hydroxy-5-methylacetophenone)

DOI: 10.1039/DT9910000241

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 241 - 247 (1991)

Update date:2022-08-04

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Authors:

Power, Michael B.

Bott, Simon G.

Bishop, Elizabeth J.

Tierce, Kelli D.

Atwood, Jerry L.

Barron, Andrew R.

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Article abstract of DOI:10.1039/DT9910000241

The reaction of (Hdbmp = 2,6-di-tert-butyl-4-methylphenol) with O=C(Cl)Me leads to acylation of one of the dbmp ligands and affords 1 (Hbhmap = 3-tert-butyl-2-hydroxy-5-methylacetophenone).Hydrolysis of 1 yields uncomplex

Full text of DOI:10.1039/DT9910000241

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