Synthesis and reactivity studies of 2,4-(dimethylmethano)-2,4-didehydroadamantane: A comparison with an unsubstituted analogue

DOI: 10.1021/jo00088a018

Source and publish data:

Journal of Organic Chemistry p. 2374 - 2380 (1994)

Update date:2022-09-26

Topics:

Authors:

Mlinaric-Majerski

Cvitas Cvitas

Veljkovic

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00088a018

We prepared 2,4-(dimethylmethano)-2,4-didehydroadamantane (1), a gem-dimethyl[3.1.1]propellane, and systematically examined its chemical behavior in relation to its unsubstituted analogue 2,4-methano-2,4-didehydroadamantane (2). 2,4-(Dimethylmethano)-2,4-

Full text of DOI:10.1021/jo00088a018

Products guided by the article

Product name:2,4-Dihydroxy-2-isopropyladamantane

Cas No:134150-35-9

R&D Labs maybe for 134150-35-9

Hefei Highzone Fine Chemical S&T CO.,LTD

Contact:86-0551-63663560

Address:room 1801 NO. 24 Shuguang RD.
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Shandong Loyal Chemical industrial Co.,Ltd

Contact:0533-7451788

Address:Linzi Chemical Industrial Park, Zibo, Shandong Province
Changyi Xinxing Technology Development Co., Ltd.

Contact:0086-510-86651065(Time Zone:8),86651656

Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Shenzhen Sunrising Industry Co., ltd.

Contact:+86 755 86571158 / 86571159 / 86571160

Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA

Relevant to this article

Diastereoselective access to nonracemic 2-cis-substituted and 2,6-cis-disubstituted piperidines

Doi:10.1021/ol202796w
(2011)
Chelation and non-chelation controlled stereoselective reduction of a-methoxy-a-phenylthio ketones

Doi:10.1016/S0040-4020(01)80909-1
(1991)
Gaining in pan-affinity towards sigma 1 and sigma 2 receptors. SAR studies on arylalkylamines

Doi:10.1016/j.bmc.2016.10.005
(2017)
Synthesis of 3-{4-[4-dimethylamino-6-(4-methyl-2-oxo-2Hchromen-7-yloxy)-[1, 3,5]triazin-2-ylamino]-phenyl}-2-phenyl-5- (4-pyridin-2-yl-piperazin-1-ylmethyl) -thiazolidin-4-one and their biological evaluation

Doi:10.1007/s00044-011-9822-y
(2012)
Isocyanide-based multicomponent reactions: Synthesis of alkyl-2-(1-(alkylcarbamoyl)-2,2-dicyanoethyl)benzoate and isochromeno[3,4-b] pyrrole derivatives

Doi:10.1021/jo201908f
(2011)
Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides

Doi:10.1021/acs.orglett.0c03258
(2020)

Article Doi