Synthesis and reactivity studies of 2,4-(dimethylmethano)-2,4-didehydroadamantane: A comparison with an unsubstituted analogue

DOI: 10.1021/jo00088a018

Source and publish data:

Journal of Organic Chemistry p. 2374 - 2380 (1994)

Update date:2022-09-26

Topics:

Authors:

Mlinaric-Majerski

Cvitas Cvitas

Veljkovic

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00088a018

We prepared 2,4-(dimethylmethano)-2,4-didehydroadamantane (1), a gem-dimethyl[3.1.1]propellane, and systematically examined its chemical behavior in relation to its unsubstituted analogue 2,4-methano-2,4-didehydroadamantane (2). 2,4-(Dimethylmethano)-2,4-

Full text of DOI:10.1021/jo00088a018

Products guided by the article

Product name:2,4-Dihydroxy-2-isopropyladamantane

Cas No:134150-35-9

R&D Labs maybe for 134150-35-9

JIN TAN CHENG'EN CHEMICAL CO.,LTD.

Contact:86-519-82116250

Address:NO.102，village Dongfang，conomic development zone
wuxi leji biology technology co., LTD

website:http://www.lejibio.com/

Contact:18362718864

Address:The Nanyue Road No. 2, Yixing City, Jiangsu Province
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Shanghai Coupling Pharmaceutical R&D Co., Ltd.(expird)

Contact:+86 021 50106671

Address:403 Room No.4 Buiding, No. 526 Ruiqing Road, Shanghai Zhangjiang Hi-Tech Park

Relevant to this article

Diastereoselective access to nonracemic 2-cis-substituted and 2,6-cis-disubstituted piperidines

Doi:10.1021/ol202796w
(2011)
Chelation and non-chelation controlled stereoselective reduction of a-methoxy-a-phenylthio ketones

Doi:10.1016/S0040-4020(01)80909-1
(1991)
Gaining in pan-affinity towards sigma 1 and sigma 2 receptors. SAR studies on arylalkylamines

Doi:10.1016/j.bmc.2016.10.005
(2017)
Synthesis of 3-{4-[4-dimethylamino-6-(4-methyl-2-oxo-2Hchromen-7-yloxy)-[1, 3,5]triazin-2-ylamino]-phenyl}-2-phenyl-5- (4-pyridin-2-yl-piperazin-1-ylmethyl) -thiazolidin-4-one and their biological evaluation

Doi:10.1007/s00044-011-9822-y
(2012)
Isocyanide-based multicomponent reactions: Synthesis of alkyl-2-(1-(alkylcarbamoyl)-2,2-dicyanoethyl)benzoate and isochromeno[3,4-b] pyrrole derivatives

Doi:10.1021/jo201908f
(2011)
Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides

Doi:10.1021/acs.orglett.0c03258
(2020)

Article Doi