Helvetica Chimica Acta p. 304 - 308 (1991)
Update date:2022-08-03
Topics:
Laali, Kenneth K.
Gao, Hong
Homolytic dediazoniation of tribromo- and trichloro-benzenediazonium tetrafluoroborates in highly ionizing, low-nucleophilicity solvents (trifluoroethanol and trifluoromethanesulfonic acid (TfOH)) exhibits a strong magnetic-field dependency of dediazoniation products; a more facile singlet-to-triplet intersystem crossing results in increased radical-escape products at higher magnetic fields.
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