New C-N-C Bond Formation Reaction using the Nitrogenation-transmetallation Process

DOI: 10.1039/c39910000081

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 81 - 83 (1991)

Update date:2022-08-02

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Authors:

Uozumi, Yasuhiro

Mori, Miwako

Shibasaki, Masakatau

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Article abstract of DOI:10.1039/c39910000081

Ketones and aryl or vinyl halides couple to give divinyl or arylvinyl amines in the presence of the titanium isocyanate complex <3THF*Mg2Cl2O*TiNCO> 1 and a palladium catalyst, via transmetallation of the titano imine complex 6 with aryl or vinyl palladium bromide (THF tetrahydrofuran).

Full text of DOI:10.1039/c39910000081

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