Bulletin of the Chemical Society of Japan p. 3163 - 3173 (1992)
Update date:2022-07-29
Topics:
Shibata, Koichi
Mitsunobu, Oyo
The reactions of 2-(2-oxoalkylseleno)benzothiazoles with allylic Grignard reagents in the presence of BF3*OEt2 gave the corresponding 2-<(2-alkyl-2-hydroxy-4-pentenyl or 2-alkyl-2-hydroxy-4-methyl-4-pentenyl)seleno>benzothiazoles which, on treatment with Ph3P and NaH, afforded 1,4-dienes in good to excellent yields.
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