Intramolecular Dissociative Isomerization and the Presence of Trans Influence in 12-Sb-6 Ate Complexes and Their Protonolysis

DOI: 10.1021/ja00188a049

Source and publish data:

Journal of the American Chemical Society p. 2276 - 2283 (1989)

Update date:2022-07-29

Topics:

Authors:

Yamamoto, Yohsuke

Fujikawa, Hisao

Fujishima, Hiroshi

Akiba, Kin-ya

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Article abstract of DOI:10.1021/ja00188a049

The reaction of methyllithium with 3,3-bis(trifluoromethyl)-1,1,1-tris(p-methylphenyl)-3H-2,1-benzoxastilbole (10-Sb-5, 2a) gave a 12-Sb-6 ate complex (5a).At -78 deg C a single isomer (5aA) with the methyl group cis to the oxygen atom was formed. (19)F N

Full text of DOI:10.1021/ja00188a049

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