Tetrahedron Letters p. 1125 - 1128 (1991)
Update date:2022-08-04
Topics:
Chiara, Jose Luis
Cabri, Walter
Hanessian, Stephen
Aliphatic 1,5- and 1,6 dialdehydes with and without α-substituents, as well as derivatives of carbohydrate dialdehydes undergo a pinacol coupling reaction in the presence of SmI2 to give cis-diols as the preponderant products. When α-alkoxy groups are present, the diol has an orientation that is opposite to such groups.
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