Carbohydrate Research p. 245 - 260 (1991)
Update date:2022-09-26
Topics:
Kawai
Chin
Just
The synthesis of the branched-chain thiosugar derivatives 8 and 13 from 1,2-O-isopropylidene-D-xylofuranose is described. The acetolytic cleavage of the acetonide group from 8 and 13 was found to yield products arising from opening of the furanose ring when carried out at low temperatures. These include the novel thiolanes 9 and 17. The desired 1,2-di-O-acetyl furanoses 6 and 14 were obtained when the reaction was performed at higher temperatures.
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Doi:10.1007/BF00958585
(1991)Doi:10.1002/ardp.19913240711
(1991)Doi:10.1021/acs.jmedchem.8b01572
(2019)Doi:10.1021/ja00016a079
(1991)Doi:10.1111/cbdd.13900
(2021)Doi:10.1039/c1dt11337b
(2011)