Stereoselective Synthesis of Seven-Membered Carbocycles by a Tandem Cyclopropanation/Cope Rearrangement between Rhodium(II)-Stabilized Vinylcarbenoids and Dienes

DOI: 10.1021/jo00012a011

Source and publish data:

Journal of Organic Chemistry p. 3817 - 3824 (1991)

Update date:2022-07-29

Topics:

Authors:

Davies, Huw M. L.

Clark, T. Jeffrey

Smith, H. David

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Article abstract of DOI:10.1021/jo00012a011

Rhodium(II)-catalyzed decomposition of vinyldiazomethanes in the presence of dienes generated 1,4-cycloheptadienes by a tandem cyclopropanation/Cope rearrangement.Excellent stereocontrol of up to three stereogenic centers in the cycloheptadienes was achie

Full text of DOI:10.1021/jo00012a011

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