Stereoselective Synthesis of Seven-Membered Carbocycles by a Tandem Cyclopropanation/Cope Rearrangement between Rhodium(II)-Stabilized Vinylcarbenoids and Dienes

DOI: 10.1021/jo00012a011

Source and publish data:

Journal of Organic Chemistry p. 3817 - 3824 (1991)

Update date:2022-07-29

Topics:

Authors:

Davies, Huw M. L.

Clark, T. Jeffrey

Smith, H. David

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00012a011

Rhodium(II)-catalyzed decomposition of vinyldiazomethanes in the presence of dienes generated 1,4-cycloheptadienes by a tandem cyclopropanation/Cope rearrangement.Excellent stereocontrol of up to three stereogenic centers in the cycloheptadienes was achie

Full text of DOI:10.1021/jo00012a011

Products guided by the article

Product name:ethyl 3-(phenylsulfonyl)cyclohepta-1,3,5-trien-1-oate

Cas No:134455-10-0

R&D Labs maybe for 134455-10-0

SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Hangzhou Taiyan Trading Co., Ltd(expird)

Contact:+86-13777583958

Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Suzhou Chiral Pharmaceuticals Co., Ltd.

Contact:86-0512-63197058

Address:Building A, No. 2358, Chang'an Road, Wujiang Science Park
Sichuan Mianzhu Ronghong Chemical Co.,LTd

Contact:8613981840544

Address:XINSHI INDUSTRY PARK,MIANZHU,SICHUAN,CHINA
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD

Relevant to this article

Urease covalently immobilized on cotton-derived nanocellulose-dialdehyde for urea detection and urea-based multicomponent synthesis of tetrahydro-pyrazolopyridines in water

Doi:10.1039/c9ra05240b
(2019)
Synthesis of novel nithiazine analogues containing the 1,4-dihydropyridine structure, and their bioactivity as insecticides

Doi:10.1007/s11164-013-1020-8
(2014)
An expeditious synthesis of an analogue of (-)-steviamine by way of the 1,3-dipolar cycloaddition of a nitrile oxide with a 1-C-allyl iminosugar

Doi:10.1016/j.tetlet.2011.09.065
(2011)
Unanticipated retention of configuration in the DAST fluorination of deoxy-4′-thiopyrimidine nucleosides with "up" hydroxyl groups

Doi:10.1016/S0040-4039(00)78345-6
(1994)
C(sp²)-C(sp²) Reductive Elimination from Well-Defined Diarylgold(III) Complexes

Doi:10.1021/acs.organomet.7b00588
(2017)
Synthesis of (+/-)-Cycloprop-G, the Cyclopropyl Analogue of the Broad Spectrum Antiviral Agent Cyclobut-G

Doi:10.1039/c39920000128
(1992)

Article Doi