CYCLOAROMATIZATION OF α-OXOKETENDITHIOACETALS WITH BENZYLMAGNESIUM CHLORIDE: A NOVEL NAPHTHALENE ANNELATION REACTION

DOI: 10.1016/S0040-4039(00)83956-8

Source and publish data:

Tetrahedron Letters p. 117 - 120 (1986)

Update date:2022-07-30

Topics:

Authors:

Balu, Maliakel P.

Singh, Gurdeep

Ila, Hiriyakkanavar

Junjappa, Hiriyakkanavar

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Article abstract of DOI:10.1016/S0040-4039(00)83956-8

α-Oxoketendithioacetals derived from acyclic and cyclic ketones are shown to react with benzylmagnesium chloride to give novel naphthoannelated aromatic compounds by sequential 1,4- and 1,2-additions followed by subsequent cycloaromatization of the resulting carbinols.

Full text of DOI:10.1016/S0040-4039(00)83956-8

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