The formation of alkenedithiocarboxylate and alkenecarboxylate ligands by insertion of CS2 and CO2 into ruthenium(II)-alkenyl bonds

DOI: 10.1016/0022-328X(91)86387-6

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 239 (1991)

Update date:2022-08-03

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Authors:

Loumrhari, Hassane

Ros, Josep

Yanez, Ramon

Torres, M. Rosario

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Article abstract of DOI:10.1016/0022-328X(91)86387-6

The unsaturated alkenyl complexes Ru(CO)Cl(RC=CHR')(PPh3)2 react with CS2 and CO2 to give Ru(CO)Cl(S2CRC=CHR')(PPh3)2 and Ru(CO)Cl(O2CRC=CHR')(PPh3)2 complexes, respectively.The products are hexacoordinated-ruthenium(II) complexes containing alkenedithioc

Full text of DOI:10.1016/0022-328X(91)86387-6

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