Tetrahedron Letters p. 3389 - 3392 (1981)
Update date:2022-07-29
Topics:
Wistuba, Eckehardt
Ruechardt, Christoph
The migration aptitudes of cyclic and polycyclic bridgehead groups in the Criegee Rearrangement support ?-neighbouring group participation by pentacoordinated bonding and vertical charge stabilisation in the migrating group and therefore favour transition state 2b and not 2a.
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