MIGRATION APTITUDES OF CYCLIC AND POLYCYCLIC BRIDGEHEAD GROUPS IN THE CRIEGEE REARRANGEMENT

DOI: 10.1016/S0040-4039(01)81913-4

Source and publish data:

Tetrahedron Letters p. 3389 - 3392 (1981)

Update date:2022-07-29

Topics:

Authors:

Wistuba, Eckehardt

Ruechardt, Christoph

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Article abstract of DOI:10.1016/S0040-4039(01)81913-4

The migration aptitudes of cyclic and polycyclic bridgehead groups in the Criegee Rearrangement support ?-neighbouring group participation by pentacoordinated bonding and vertical charge stabilisation in the migrating group and therefore favour transition state 2b and not 2a.

Full text of DOI:10.1016/S0040-4039(01)81913-4

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