Asymmetric aldol reaction: A highly erythro-selective aldol reaction between tricarbonyl(A-trimethylsilylbenzaldehyde derivative )-chromium (0) complexes and cyclic silyl enol ethers

DOI: 10.1016/S0040-4020(01)96032-6

Source and publish data:

Tetrahedron p. 3007 - 3036 (1991)

Update date:2022-07-29

Topics:

Authors:

Mukai, Chisato

Cho, Won Jea

Kim, In Jong

Kido, Masaru

Hanaoka, Miyoji

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Article abstract of DOI:10.1016/S0040-4020(01)96032-6

Reaction of (±)-chromium (0) -complexes 4e-g with 5-7 gave the erythro isomers in a highly selective manner. This aldol reaction was successfully applied to the asymmetric one. The absolute configuration was determined by X-ray analysis of (-)-erythro-8e.

Full text of DOI:10.1016/S0040-4020(01)96032-6

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