A Facile Synthesis of 4-Alkoxymethylphenols by a Copper(II)-Acetoxime Catalyst/O2 System

DOI: 10.1016/S0040-4039(00)78906-4

Source and publish data:

Tetrahedron Letters p. 2053 - 2056 (1991)

Update date:2022-07-30

Topics:

Authors:

Shimizu, Masao

Watanabe, Yoshihito

Orita, Hideo

Hayakawa, Takashi

Takehira, Katsuomi

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Article abstract of DOI:10.1016/S0040-4039(00)78906-4

4-Alkoxymethyl-2,6-dimethylphenols were synthesized from 2,4,6-trimethylphenol in good yields by a copper(II) chloride-acetoxime catalyst/molecular oxygen system in alcohols at ambient temperature.The oxidation of the other p-methylsubstituted phenols were also examined.

Full text of DOI:10.1016/S0040-4039(00)78906-4

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Product name:4-(cyclohexyloxymethyl)-2,6-dimethylphenol

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